Product ID:PROTURF FLUID BROADLEAF WEED CONTROL, 8675
MSDS Date:02/19/1997
FSC:6840
NIIN:00N084414
MSDS Number: CGSWF

SCOTTS CO

14111 SCOTTSLAWN RD
MARYSVILLE, OH 43041
US

Emergency Phone: 513-644-0011

Info Phone: 513-644-0011

Cage: HO561

SCOTTS CO

MARYSVILLE, OH 43041 US

Telephone: 513-644-0011

Cage: HO561

DIMETHYLAMINE SALT OF 2,4-DICHLOROPHENOXYACETIC ACID

CAS: 742-19-8

RTECS: 9999999ZZ

OSHA PEL 10 MG/M3 (MFR)

ACGIH TLV: 10 MG/M3 (MFR)

2-(2,4-DICHLOROPHENOXY) PROPIONIC ACID DIETHANOLAMINE SALT;

CAS: 84731-66-8

OSHA PEL N/K

ACGIH TLV: N/K

PROPIONIC ACID (2,4-DP, DIMETHYLAMINE SALT))

RTECS: 9999999ZZ

OSHA PEL N/K

ACGIH TLV: N/K

BE FOUND IN URINE. ELEVATIONS IN LACTATE

RTECS: 9999999ZZ

MUSCLE DMG. IT HAS BEEN SUGGESTED THAT OVEREXP IN

RTECS: 9999999ZZ

ACUTE EFTS ON CNS RESEMBLE THOSE PRDCD BY

RTECS: 9999999ZZ

REDUCED NERVE CONDUCT VELOCITIES HAVE BEEN REPORTED

RTECS: 9999999ZZ

FACTORS. GAS-LIQ CHROMATOGRAPHY FOR DETECTING &

RTECS: 9999999ZZ

USEFUL IN CONFIRMING & ASSESSING MAGNITUDE OF

RTECS: 9999999ZZ

FOR DISP. IF SPILLED ON GROUND, AFFECTED AREA

RTECS: 9999999ZZ

APPROP CNTNR FOR DISP. DO NOT FLUSH MATL TO PUBLIC

RTECS: 9999999ZZ

EQUIPMENT DURING CLEANUP ACTIVITIES. ENSURE ADEQUATE

RTECS: 9999999ZZ

LD50 LC50 Mixture:LD50:(ORAL,RAT) 998 MG/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:DANGER:CAUSES IRREVERSIBLE EYE
DAMAGE SEEN AS CORNEAL OPACITY. VAPORS OR SPRAYS (MISTS) ARE
IRRITATING TO EYES. HARMFUL IF SWALLOWED. MAY CAUSE NAUSEA,
VOMITING, ABDOMINAL PAINS, MYOTONIA, MUSCL E WEAKNESS AND FALL IN
BLOOD PRESSURE. HARMFUL IF INHALED. MAY BE IRRITATING TO THE
RESPIRATORY TRACT. (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:CHRONIC:REPEATED OVEREXP TO 2,4-D
HERBICIDES MAY CAUSE LIVER, KIDNEY, GI & MUSCULAR EFTS. RARE CASES
OF PERIPHERAL NERVE DMG HAVE BEEN REPORTED, BUT EXTENSIVE ANIMAL
STUDIES HAVE FAILED TO SU BSTANTIATE THESE OBSERVATIONS, EVEN AT
HIGH DOSES FOR PROLONGED PERIODS.
Medical Cond Aggravated by Exposure:SKIN IRRITATION MAY BE AGGRAVATED
IN PERSONS W/EXISTING SKIN LESIONS. BREATHING OF VAPORS OR SPRAYS
MAY AGGRAVATE ACUTE OR CHRONIC ASTHMA & INFLAMMATORY OR FIBROTIC
PULMONARY DISEASE.

First Aid:EYES:FLUSH W/WATER FOR AT LST 15 MINS HOLDING LIDS OPEN. GET
MED ATTN, PREF OPTHALMOLOGIST. SKIN:WASH THORO. IF IRRIT PERSISTS,
GET MED ATTN. INHAL:REMOVE TO FRESH AIR. TREAT SYMPTOMATICALLY. GET
MED ATTN. INGEST:INDUCE VOMIT/GASTRIC LAVAGE IF LG AMTS INGESTED.
TREAT SYMPTOMATIC & SUPPORTIVE. GET MED ATTN. NOTES TO MD:NO
SPECIFIC ANTIDOTE IS AVAIL. TREAT SYMPTOMATICALLY. OVEREXP TO MATLS
(SUPDAT)

Extinguishing Media:USE CARBON DIOXIDE OR DRY CHEMICAL FOR SMALL FIRES.
USE WATER SPRAY OR FOAM (ALCOHOL, POLYMER OR ORDINARY) FOR LG
FIRES.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:COMBUSTION PRODUCTS MAY BE HAZARDOUS.
THESE MAY INCLUDE HYDROGEN CHLORIDE, NITROGEN OXIDES, CARBON
MONOXIDE & CARBON DIOXIDE.

Spill Release Procedures:READ LBL. DIKE LG SPILLS USING
ABSORB/IMPERVIOUS MATLS SUCH AS SAND/CLAY. RECOVER REMAINING
SPILLED MATL AS APPROP. COLLECT & CONTAIN CONTAM ABSORB & DIKE MATL
FOR DISP. ABSORB SM SPILLS ON SAND/VERMI CULITE. PLACE CONTAM MATLS
IN APPROP CNTNR(ING 10)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:READ LABEL FOR STORAGE & DISPOSAL
INSTRUCTIONS. KEEP OUT OF REACH OF CHILDREN. DO NOT GET IN EYES. DO
NOT INGEST. AVOID EXPOSURE BY INHALATION.
Other Precautions:AVOID GETTING ON SKIN OR ON CLOTHING. DO NOT STORE
NEAR FEED OR FOODSTUFFS, SEEDS, FERTILIZERS, INSECTICIDES OR
FUNGICIDES. DO NOT CONTAMINATE WATER, FOOD OR FEED BY STORAGE OR
DISPOSAL.

Respiratory Protection:USE NIOSH APPROVED RESPIRATOR FOR PESTICIDE MIST
WHEN HANDLING SPILLS OR LEAKS OR WHEN AIRBORNE CONCENTRATIONS
EXCEED ALLOWABLE EXPOSURE LIMITS.
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Protective Gloves:RUBBER GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS &(SUPDAT)
Other Protective Equipment:ANSI APPROVED EYE WASH FOUNTAIN & DELUGE
SHOWER . LONG PANTS, LONG-SLEEVED SHIRT, SOCKS & SHOES.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EYE PROT:FULL LGTH FSHLD . FIRST AID PROC:OTHER THAN THIS PROD MAY HAVE
OCCURRED. THIS PROD CONTAINS SALTS OF TWO PHENOXY HERBICIDE CHEMS.
MYOTOXIC EFTS MAY INCL MUSCLE FIBRILLATIONS, MYOTONIA & MUSCULAR
WEAK. INGEST OF MASSIVE DOSESMAY RSLT IN PERSISTENT FALL OF BLOOD
PRESS. MYOGLOBIN & HEMOGLOBIN MAY (ING 4)

Spec Gravity:202 (H*2O=1)
Solubility in Water:AQUEOUS SOLUTION
Appearance and Odor:AMBER TO BROWN LIQUID; PHENOXY ODOR.

Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, OXIDIZERS.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:HYDROGEN CHLORIDE, NITROGEN OXIDES,
CARBON MONOXIDE & CARBON DIOXIDE MAY BE PRODUCED UPON
DECOMPOSITION.

Waste Disposal Methods:READ LABEL. DISPOSE OF I/A/W LOCAL, STATE &
FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.